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Ethyl acrylate cleanup levels in Texas

  • TCEQ
  • TRRP Tier 1 PCLs
  • CAS 140-88-5
  • February 6, 2025

For Ethyl acrylate, TCEQ's Tier 1 table prints 130 mg/kg for TotSoilComb and 0.12 mg/kg for GWSoilIng (residential soil, 0.5 acre source area), and 0.019 mg/L for GWGWIng (residential groundwater).

  • 130mg/kg 1.3E+02 TotSoilComb Table 1: Tier 1 Residential Soil PCLs 0.5 acre source area
  • 0.12mg/kg 1.2E-01 GWSoilIng Table 1: Tier 1 Residential Soil PCLs 0.5 acre source area
  • 0.019mg/L 1.9E-02 GWGWIng Table 3: Tier 1 Groundwater PCLs - Residential and Commercial/Industrial Residential

These are the Texas Commission on Environmental Quality's published values for Ethyl acrylate, from its Texas Risk Reduction Program Tier 1 Protective Concentration Levels, last revised February 6, 2025. Each value is shown as the agency prints it, with the same number written out beside it.

Texas: Texas Risk Reduction Program Tier 1 Protective Concentration Levels

Table 1: Tier 1 Residential Soil PCLs1

0.5 acre source area
ColumnValueWritten outnote3
TotSoilComb2 (mg/kg)1.3E+02130c
GWSoilIng (mg/kg)1.2E-010.12c
GWSoilClass 3 (mg/kg)1.2E+0112c
AirSoilInh-V4 (mg/kg)2.4E+02240n
AirGW-SoilInh-V (mg/kg)6.8E+036,800n
GWSoil for Secondary MCL (mg/kg)─
30 acre source area
ColumnValueWritten outnote3
TotSoilComb2 (mg/kg)9.6E+0196n
GWSoilIng (mg/kg)5.9E-020.059c
GWSoilClass 3 (mg/kg)5.9E+005.9c
AirSoilInh-V4 (mg/kg)1.2E+02120n
AirGW-SoilInh-V (mg/kg)4.4E+02440n
GWSoil for Secondary MCL (mg/kg)─
Footnotes to Table 1, as the agency prints them

1 In accordance with §350.72(b), when establishing Tier 1 PCLs for individual COCs for each of the individual and combined human health exposure pathways, the person must evaluate whether the PCLs need to be adjusted to lower concentrations to meet the cumulative carcinogenic risk level and hazard index criteria specified in §350.72(c). For COCs which exhibit both carcinogenic and noncarcinogenic characteristics, they shall be evaluated as both a carcinogen and noncarcinogen when determining whether the PCL established for an individual COC for each of the individual and combined human health exposure pathways needs to be adjusted to a lower concentration to meet the cumulative risk and hazard criteria. The person shall then use the lower of the carcinogenic or noncarcinogenic PCL as the Tier 1 human health PCL. In other words, the Tier 1 PCLs provided in this table for an individual COC should not be used as the final Tier 1 human health PCL for any of the individual or combined exposure pathways in cases where there are more than 10 carcinogenic and/or more than 10 noncarcinogenic COCs within a source medium unless it can be demonstrated that further downward adjustment is not necessary to meet the cumulative risk and hazard criteria.

2 Combined includes inhalation; ingestion; dermal; vegetable consumption pathways

3 c = carcinogenic; n = noncarcinogenic; m = primary MCL-based; e = EPA Action Level-based; > S = solubility limit exceeded during calculation

4 For subsurface soils only

5 Site-specific PCLs for mercury may vary based on the pH-dependent Kd value (see Figure:30 TAC §350.73(f)(1)(C)). Persons should use the Tier 1 pH 4.9-based PCLs unless a site-specific soil pH > 6.8 is demonstrated with site-specific soil samples.

6 Persons must use the value provided in the "GWSoil for Secondary MCL" column of this table as the GWSoil PCL for MTBE if the conditions described in §350.74(f)(3) exist.

7 Please see the note on nitrate/nitrite in the "List of Updates" spreadsheet for March 31, 2017.

8 This chemical is one of four chemicals that make up total trihalomethanes (TTHMs). USEPA has established an MCL for TTHMs of 0.08 mg/L. Each individual chemical that contributes to TTHMs must meet the 0.08 mg/L based GWSoilIng PCL, and the person must ensure that the total soil concentrations for all four will not impact groundwater above the GWGWIng based MCL.

9 Nitrate, nitrite, and ammonia are inorganic anions that are mobile in most environmental situations, quickly partitioning from soil to groundwater. Due to these partitioning characteristics it is difficult to calculate a reliable soil-water partition coefficient (Kd) and Henry’s law constant (H’) for these compounds. The Kd and H’ are parameters that are required to calculate the GWSoilIng PCL in accordance with 30 TAC 350.75(b)(1) using the Tier 1 GWSoilIng PCL equation.

* These compounds are not necessarily of concern from a human health standpoint, therefore calculation of human health-based values is not required. However, aesthetics and ecological criteria would still apply. See table entitled "Compounds for which Calculation of a Human Health PCL is Not Required" available on the TCEQ website at http://www.tceq.state.tx.us/remediation/trrp/trrp.html.

NA=Not applicable

All values capped at 1.0E+06

This table shows the residiential soil protective concentration levels for both 0.5 acre and 30 acre source areas

Table 2: Tier 1 Commercial/Industrial Soil PCLs1

0.5 acre source area
ColumnValueWritten outnote3
TotSoilComb2 (mg/kg)3.2E+02320n
GWSoilIng (mg/kg)2.7E-010.27c
GWSoilClass 3 (mg/kg)2.7E+0127c
AirSoilInh-V4 (mg/kg)3.4E+02340n
AirGW-SoilInh-V (mg/kg)9.6E+039,600n
GWSoil for Secondary MCL (mg/kg)─
30 acre source area
ColumnValueWritten outnote3
TotSoilComb2 (mg/kg)1.7E+02170n
GWSoilIng (mg/kg)1.3E-010.13c
GWSoilClass 3 (mg/kg)1.3E+0113c
AirSoilInh-V4 (mg/kg)1.7E+02170n
AirGW-SoilInh-V (mg/kg)6.2E+02620n
GWSoil for Secondary MCL (mg/kg)─
Footnotes to Table 2, as the agency prints them

1 In accordance with §350.72(b), when establishing Tier 1 PCLs for individual COCs for each of the individual and combined human health exposure pathways, the person must evaluate whether the PCLs need to be adjusted to lower concentrations to meet the cumulative carcinogenic risk level and hazard index criteria specified in §350.72(c). For COCs which exhibit both carcinogenic and noncarcinogenic characteristics, they shall be evaluated as both a carcinogen and noncarcinogen when determining whether the PCL established for an individual COC for each of the individual and combined human health exposure pathways needs to be adjusted to a lower concentration to meet the cumulative risk and hazard criteria. The person shall then use the lower of the carcinogenic or noncarcinogenic PCL as the Tier 1 human health PCL. In other words, the Tier 1 PCLs provided in this table for an individual COC should not be used as the final Tier 1 human health PCL for any of the individual or combined exposure pathways in cases where there are more than 10 carcinogenic and/or more than 10 noncarcinogenic COCs within a source medium unless it can be demonstrated that further downward adjustment is not necessary to meet the cumulative risk and hazard criteria.

2 Combined includes inhalation; ingestion; dermal pathways

3 c = carcinogenic; n = noncarcinogenic; m = primary MCL-based; e = EPA Action Level-based; > S = solubility limit exceeded during calculation

4 For subsurface soils only

5 Site-specific PCLs for mercury may vary based on the pH-dependent Kd value (see Figure:30 TAC §350.73(f)(1)(C)). Persons should use the Tier 1 pH 4.9-based PCLs unless a site-specific soil pH > 6.8 is demonstrated with site-specific soil samples.

6 Persons must use the value provided in the "GWSoil for Secondary MCL" column of this table as the GWSoil PCL for MTBE if the conditions described in §350.74(f)(3) exist.

7 Please see the note on nitrate/nitrite in the "List of Updates" spreadsheet for March 31, 2017.

8 This chemical is one of four chemicals that make up total trihalomethanes (TTHMs). USEPA has established an MCL for TTHMs of 0.08 mg/L. Each individual chemical that contributes to TTHMs must meet the 0.08 mg/L based GWSoilIng PCL, and the person must ensure that the total soil concentrations for all four will not impact groundwater above the GWGWIng based MCL.

9 Nitrate, nitrite, and ammonia are inorganic anions that are mobile in most environmental situations, quickly partitioning from soil to groundwater. Due to these partitioning characteristics it is difficult to calculate a reliable soil-water partition coefficient (Kd) and Henry’s law constant (H’) for these compounds. The Kd and H’ are parameters that are required to calculate the GWSoilIng PCL in accordance with 30 TAC 350.75(b)(1) using the Tier 1 GWSoilIng PCL equation.

* These compounds are not necessarily of concern from a human health standpoint, therefore calculation of human health-based values is not required. However, aesthetics and ecological criteria would still apply. See table entitled "Compounds for which Calculation of a Human Health PCL is Not Required" available on the TCEQ website at http://www.tceq.state.tx.us/remediation/trrp/trrp.html.

NA=Not applicable

All values capped at 1.0E+06

This table shows the commerical/industrial protective concentration levels for 0.5 and 30 acre source areas

Table 3: Tier 1 Groundwater PCLs - Residential and Commercial/Industrial1

Residential
ColumnValueWritten outnote4
GWGWIng2 (mg/L)1.9E-020.019c
GWGWClass33 (mg/L)1.9E+001.9c
AirGWInh-V 0.5 acre source area (mg/L)1.1E+031,100n
AirGWInh-V 30 acre source area (mg/L)1.4E+02140n
Commercial/Industrial
ColumnValueWritten outnote4
GWGWIng2 (mg/L)4.3E-020.043c
GWGWClass33 (mg/L)4.3E+004.3c
AirGWInh-V 0.5 acre source area (mg/L)1.5E+031,500n
AirGWInh-V 30 acre source area (mg/L)2.0E+02200n
NA
ColumnValueWritten out
Secondary MCL5 (mg/L)─
Footnotes to Table 3, as the agency prints them

1 In accordance with §350.72(b), when establishing Tier 1 PCLs for individual COCs for each of the individual and combined human health exposure pathways, the person must evaluate whether the PCLs need to be adjusted to lower concentrations to meet the cumulative carcinogenic risk level and hazard index criteria specified in §350.72(c). For COCs which exhibit both carcinogenic and noncarcinogenic characteristics, they shall be evaluated as both a carcinogen and noncarcinogen when determining whether the PCL established for an individual COC for each of the individual and combined human health exposure pathways needs to be adjusted to a lower concentration to meet the cumulative risk and hazard criteria. The person shall then use the lower of the carcinogenic or noncarcinogenic PCL as the Tier 1 human health PCL. In other words, the Tier 1 PCLs provided in this table for an individual COC should not be used as the final Tier 1 human health PCL for any of the individual or combined exposure pathways in cases where there are more than 10 carcinogenic and/or more than 10 noncarcinogenic COCs within a source medium unless it can be demonstrated that further downward adjustment is not necessary to meet the cumulative risk and hazard criteria.

2 based on primary MCLs when available

3 100 x GWGWIng

4 c = carcinogenic; n = noncarcinogenic; m = primary MCL-based; e = EPA Action Level-based; > S = solubility limit exceeded during calculation

5 The Secondary MCL values for ammonia and MTBE are based on taste and odor.

6 This chemical is one of four chemicals that make up total trihalomethanes (TTHMs). USEPA has established an MCL for TTHMs of 0.08 mg/L, so neither the individual concentration for any of these four chemicals can exceed the MCL, nor the total additive concentration of these four chemicals can exceed the MCL.

7 Dibenz-a,h-anthracene does not have an MCL. However, the relative potency factor for dibenz-a,h-anthracene is equal to the potency factor for benzo-a-pyrene and is treated like benzo-a-pyrene for groundwater pathways.

8 Persons must use the value provided in the "Secondary MCL" column of this table as the GWGWIng PCL for MTBE if the conditions described in §350.74(f)(3) exist.

9 Please see the note on nitrate/nitrite in the "List of Updates" spreadsheet for March 31, 2017.

* These compounds are not necessarily of concern from a human health standpoint, therefore calculation of human health-based values is not required. However, aesthetics and ecological criteria would still apply. See table entitled "Compounds for which Calculation of a Human Health PCL is Not Required" available on the TCEQ website at http://www.tceq.state.tx.us/remediation/trrp/trrp.html.

NA = not applicable

All values capped at 1E+06

This table shows the protective groundwater concentrations for residential and commercial/industrial land with 0.5 acre and 30 acre source areas

The agency's current table governs. This page is a reference copy and not a cleanup decision. Check the agency's page for a newer table before relying on a value.

Source

Maintained by Barrow. General reference only, not legal or professional advice. Barrow is not affiliated with or endorsed by any government agency. See how Barrow drafts the report